Issue 38, 2012
From the journal:

Chemical Communications

Magnesium-catalysed hydroboration of aldehydes and ketones†‡

Merle Arrowsmith,a   Terrance J. Hadlington,a   Michael S. Hill*a  and  Gabriele Kociok-Köhna  

* Corresponding authors

a Department of Chemistry, University of Bath, Claverton down, Bath, UK
E-mail: msh27@bath.ac.uk

Abstract

The heteroleptic magnesium alkyl complex [CH{C(Me)NAr}2MgnBu] (Ar = 2,6-iPr2C6H3) is reported as a highly efficient pre-catalyst for the hydroboration of aldehydes and ketones with pinacolborane.

Graphical abstract: Magnesium-catalysed hydroboration of aldehydes and ketones

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Article information

DOI
https://doi.org/10.1039/C2CC30565H
Article type
Communication
Submitted
25 janv. 2012
Accepted
07 mars 2012
First published
08 mars 2012

Chem. Commun., 2012,48, 4567-4569

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Magnesium-catalysed hydroboration of aldehydes and ketones

M. Arrowsmith, T. J. Hadlington, M. S. Hill and G. Kociok-Köhn, Chem. Commun., 2012, 48, 4567 DOI: 10.1039/C2CC30565H

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