A coordination polymer of (Ph3P)AuCl prepared by post-synthetic modification and its application in 1-hexene/n-hexane separation

Ana J. Nuñez; Lindsey N. Shear; Naween Dahal; Ilich A. Ibarra; JiWoong Yoon; Young Kyu Hwang; Jong-San Chang; Simon M. Humphrey

doi:10.1039/C1CC14682C

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A coordination polymer of (Ph₃P)AuCl prepared by post-synthetic modification and its application in 1-hexene/n-hexane separation†

Ana J. Nuñez,^a Lindsey N. Shear,^a Naween Dahal,^a Ilich A. Ibarra,^a JiWoong Yoon,^b Young Kyu Hwang,^b Jong-San Chang^b and Simon M. Humphrey*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, TX, USA

^b Catalysis Center for Molecular Engineering, Korea Research Institute of Chemical Technology, PO Box 107, Yusung, Daejeon, Korea

Abstract

PCM-10 is a porous phosphine coordination material based on Ca(II) and tris(p-carboxylated) triphenylphosphine. The material provides a unique 3-dimensional surface of P(III) Lewis base sites, which is ideal for post-synthetic functionalization. The addition of Au(I) yields an advanced material that can selectively adsorb 1-hexene over n-hexane at room temperature.

This article is part of the themed collection: Celebrating the ChemComm Emerging Investigator Lectureship Winners

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C1CC14682C
Article type: Communication
Submitted: 29 juil. 2011
Accepted: 27 août 2011
First published: 07 oct. 2011

Download Citation

Chem. Commun., 2011,47, 11855-11857

Permissions

Request permissions

A coordination polymer of (Ph₃P)AuCl prepared by post-synthetic modification and its application in 1-hexene/n-hexane separation

A. J. Nuñez, L. N. Shear, N. Dahal, I. A. Ibarra, J. Yoon, Y. K. Hwang, J. Chang and S. M. Humphrey, Chem. Commun., 2011, 47, 11855 DOI: 10.1039/C1CC14682C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications