Issue 22, 2011

Calix[4]arene nitroxide tetraradical and octaradical

Abstract

1,3-Alternate calix[4]arene with para-phenylene spacers connecting nitroxide monoradicals and high-spin (S = 1) diradicals provides tetraradical and octaradical scaffolds that possess conformations with slow electron spin relaxation rates (1/T1). Such scaffolds may facilitate tuning of relaxation rates that are more favorable for MRI or DNP applications.

Graphical abstract: Calix[4]arene nitroxide tetraradical and octaradical

Supplementary files

Article information

Article type
Communication
Submitted
27 févr. 2011
Accepted
18 avr. 2011
First published
04 mai 2011

Chem. Commun., 2011,47, 6443-6445

Calix[4]arene nitroxide tetraradical and octaradical

A. Olankitwanit, V. Kathirvelu, S. Rajca, G. R. Eaton, S. S. Eaton and A. Rajca, Chem. Commun., 2011, 47, 6443 DOI: 10.1039/C1CC11172H

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