Issue 20, 2000
From the journal:

Chemical Communications

Synthesis and characterization of the monomer Ga{(NDippCMe)2CH} (Dipp = C6H3Pri2-2,6): a low valent gallium(i) carbene analogue

Ned J. Hardman,a   Barrett E. Eichlera  and  Philip P. Power*a  

* Corresponding authors

a Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, California, USA.
E-mail: E-mail: pppower@ucdavis.edu

Abstract

The reaction between solvent free Li{(NDippCMe)2CH} (Dipp = C6H3Pri2-2,6), ‘GaI’ and potassium in toluene afforded Ga{(NDippCMe)2CH} 1 which features a V-shaped, two-coordinate, six-electron gallium(I) center electronically analogous to a singlet carbene carbon.

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Article information

DOI
https://doi.org/10.1039/B005686N
Article type
Communication
Submitted
12 juil. 2000
Accepted
06 sept. 2000
First published
27 sept. 2000

Chem. Commun., 2000, 1991-1992

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Synthesis and characterization of the monomer Ga{(NDippCMe)2CH} (Dipp = C6H3Pri2-2,6): a low valent gallium(I) carbene analogue

N. J. Hardman, B. E. Eichler and P. P. Power, Chem. Commun., 2000, 1991 DOI: 10.1039/B005686N

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