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Abstract | Cited by

Fluoridating reagents are used to model interfacial reactions in fluoride-ion batteries. Topochemical F-ion insertion is seen for one-dimensional (1D) tunnel-structured FeSb2O4 but interphase formation comprising antimony (oxy)fluorides is observed for MnSb2O4.

Graphical abstract: Interphase formation versus fluoride-ion insertion in tunnel-structured transition metal antimonites

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