Issue 59, 2024
From the journal:

Chemical Communications

2D metal–organic frameworks bearing butterfly-shaped metal-bis(dithiolene) linkers from dithiol-functionalized benzenedicarboxylic acid†

Hao Zhong,a   Zhixin Jiang,a   Jieying Hu,a   Lai-Hon Chung ORCID logo *ab  and  Jun He ORCID logo *ab  

* Corresponding authors

a School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, P. R. China
E-mail: junhe@gdut.edu.cn

b Guangdong Provincial Laboratory of Chemistry and Fine Chemical Engineering Jieyang Center, Jieyang 515200, China
E-mail: laihonchung@gdut.edu.cn

Abstract

An assembly between 1,4-dicarboxylbenzene-2,3-dithiol (H2dcbdt) and different transition metal ions successfully produced 2D metal–organic frameworks (M-dcbdt, M = Ni, Co or Fe) composed of unprecedented butterfly-shaped metal-bis(dithiolene) (MS4) linkers in one-pot fashion. Such strategy provides easier access to the [MS4]-rich network and lowers the prerequisite to explore their applications.

Graphical abstract: 2D metal–organic frameworks bearing butterfly-shaped metal-bis(dithiolene) linkers from dithiol-functionalized benzenedicarboxylic acid

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Article information

DOI
https://doi.org/10.1039/D4CC02282C
Article type
Communication
Submitted
10 mai 2024
Accepted
19 juin 2024
First published
20 juin 2024

Chem. Commun., 2024,60, 7578-7581

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2D metal–organic frameworks bearing butterfly-shaped metal-bis(dithiolene) linkers from dithiol-functionalized benzenedicarboxylic acid

H. Zhong, Z. Jiang, J. Hu, L. Chung and J. He, Chem. Commun., 2024, 60, 7578 DOI: 10.1039/D4CC02282C

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