Appropriation of group II metals: synthesis and characterisation of the first alkaline earth metal supported transition metal carbonite complexes

Siad Wolff; Annabelle Ponsonby; André Dallmann; Christian Herwig; Fabian Beckmann; Beatrice Cula; Christian Limberg

doi:10.1039/D4CC01682C

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Appropriation of group II metals: synthesis and characterisation of the first alkaline earth metal supported transition metal carbonite complexes†

Siad Wolff,

^a Annabelle Ponsonby,^a André Dallmann,

^a Christian Herwig,^a Fabian Beckmann,^a Beatrice Cula^a and Christian Limberg

*^a

Author affiliations

* Corresponding authors

^a Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Straße 2, 12489 Berlin, Germany
E-mail: Christian.limberg@chemie.hu-berlin.de

Abstract

Nickel carbonite complexes supported by alkaline earth metals have been accessed via salt-metathesis of the corresponding alkali metal precursors. The new complexes undergo Schlenk-like exchange reactions in solution which have been investigated by NMR spectroscopy. Also their reactivity towards epoxides and carbon monoxide was studied.

This article is part of the themed collection: Small Molecule Transformations of Energy Relevance

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/D4CC01682C
Article type: Communication
Submitted: 10 avr. 2024
Accepted: 07 mai 2024
First published: 07 mai 2024
This article is Open Access

Download Citation

Chem. Commun., 2024,60, 5816-5819

Permissions

Request permissions

Appropriation of group II metals: synthesis and characterisation of the first alkaline earth metal supported transition metal carbonite complexes

S. Wolff, A. Ponsonby, A. Dallmann, C. Herwig, F. Beckmann, B. Cula and C. Limberg, Chem. Commun., 2024, 60, 5816 DOI: 10.1039/D4CC01682C

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

Appropriation of group II metals: synthesis and characterisation of the first alkaline earth metal supported transition metal carbonite complexes†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Appropriation of group II metals: synthesis and characterisation of the first alkaline earth metal supported transition metal carbonite complexes

Social activity

Search articles by author

Spotlight

Advertisements