Issue 43, 2024

An extremely electron poor Au(iii) trication bearing acetonitrile ligands

Abstract

The synthesis and structural characterization of an electron poor Au(III) trication bearing 2 imidazole and 2 acetonitrile ligands is described. The new complex is capable of aryl C–H metalation with the formation of a monomesitylene complex and also demonstrated to be highly oxidizing in the rapid room temperature conversion of cyclohexene to benzene.

Graphical abstract: An extremely electron poor Au(iii) trication bearing acetonitrile ligands

Supplementary files

Article information

Article type
Communication
Submitted
20 févr. 2024
Accepted
23 avr. 2024
First published
01 mai 2024

Chem. Commun., 2024,60, 5586-5589

An extremely electron poor Au(III) trication bearing acetonitrile ligands

L. Barwise, L. J. Moon, B. Dhakal, C. F. Hogan, K. F. White and J. L. Dutton, Chem. Commun., 2024, 60, 5586 DOI: 10.1039/D4CC00818A

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