Core–shell Fe3O4@CoFe2O4 nanoparticles as high-performance anode catalysts for enhanced oxygen evolution reaction

Abstract

Water electrolysis is a promising and environmentally friendly means for renewable energy storage. Recent progress in the development of anion exchange membranes (AEMs) has provided new perspectives for high-performance anode catalysts based on transition metal oxides (TMOs) for the sluggish anodic oxygen evolution reaction (OER). Here, we report on core–shell nanoparticles (Fe₃O₄@CoFe₂O₄) which allow combining an electrocatalytic shell (CoFe₂O₄) with a conductive core (Fe₃O₄). Such an original approach significantly minimizes critical Co content in the catalyst and avoids addition of unstable conductive carbon black. The core–shell nanoparticles outperform Co_(1−x)Fe_(2+x)O₄ nanoparticles and show an exceptional OER activity per Co unit mass (2800 A g_cobalt⁻¹ at 1.65 V vs. RHE) suggesting synergistic interaction between the core and the shell. Along with the core–shell structure, the size of the Fe₃O₄ core is a critical parameter, with a large conductive Fe₃O₄ core being beneficial for OER enhancement.