Carbon-based single-atom catalysts: impacts of atomic coordination on the oxygen reduction reaction

Abstract

Slow oxygen reduction reaction (ORR) kinetics is the main factor restricting the development of fuel cells and metal–air batteries. Carbon-based single-atom catalysts (SACs) have the advantages of high electrical conductivity, maximal atom utilization, and high mass activity, thus showing great potential in exploring low-cost and high-efficiency ORR catalysts. For carbon-based SACs, the defects in the carbon support, the coordination of non-metallic heteroatoms, and the coordination number have a great influence on the adsorption of the reaction intermediates, thus significantly affecting the catalytic performance. Consequently, it is of vital importance to summarize the impacts of atomic coordination on the ORR. In this review, we focus on the regulation of the central atoms and coordination atoms of carbon-based SACs for the ORR. The survey involves various SACs, from noble metals (Pt) to transition metals (Fe, Co, Ni, Cu, etc.) and major group metals (Mg, Bi, etc.). At the same time, the influence of defects in the carbon support, the coordination of non-metallic heteroatoms (such as B, N, P, S, O, Cl, etc.), and the coordination number of the well-defined SACs on the ORR were put forward. Then, the impact of the neighboring metal monomers for SACs on the ORR performance is discussed. Finally, the current challenges and prospects for the future development of carbon-based SACs in coordination chemistry are presented.