Issue 1, 2023
From the journal:

Nanoscale

Structure and assembly of a hexanuclear AuNi bimetallic nanocluster†

Cheng-Bo Tao,a   Ji-Qiang Fan,a   Wenwen Fei,a   Yan Zhao*a  and  Man-Bo Li ORCID logo *a  

* Corresponding authors

a Institute of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Anhui University, Hefei 230601, P.R. China
E-mail: 20231@ahu.edu.cn, mbli@ahu.edu.cn

Abstract

An Au4Ni2 nanocluster containing a square-planar [–PPh2–Au–S–Au–]2 ring and two nickel-pincer arms is reported here. Abundant intra- and inter-cluster noncovalent interactions promote the assembly of the nanocluster into a porous framework material. The assembly-dependent unique solubility and photoluminescence were also investigated.

Graphical abstract: Structure and assembly of a hexanuclear AuNi bimetallic nanocluster

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Article information

DOI
https://doi.org/10.1039/D2NR05225C
Article type
Communication
Submitted
22 sept. 2022
Accepted
21 nov. 2022
First published
21 nov. 2022

Nanoscale, 2023,15, 109-113

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Structure and assembly of a hexanuclear AuNi bimetallic nanocluster

C. Tao, J. Fan, W. Fei, Y. Zhao and M. Li, Nanoscale, 2023, 15, 109 DOI: 10.1039/D2NR05225C

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