Role of graphene quantum dots with discrete band gaps on SnO2 nanodomes for NO2 gas sensors with an ultralow detection limit

Abstract

NO₂ is a major air pollutant that should be monitored due to its harmful effects on the environment and human health. Semiconducting metal oxide-based gas sensors have been widely explored owing to their superior sensitivity towards NO₂, but their high operating temperature (>200 °C) and low selectivity still limit their practical use in sensor devices. In this study, we decorated graphene quantum dots (GQDs) with discrete band gaps onto tin oxide nanodomes (GQD@SnO₂ nanodomes), enabling room temperature (RT) sensing towards 5 ppm NO₂ gas with a noticeable response ((R_a/R_g) − 1 = 4.8), which cannot be matched using pristine SnO₂ nanodomes. In addition, the GQD@SnO₂ nanodome based gas sensor shows an extremely low detection limit of 1.1 ppb and high selectivity compared to other pollutant gases (H₂S, CO, C₇H₈, NH₃, and CH₃COCH₃). The oxygen functional groups in GQDs specifically enhance NO₂ accessibility by increasing the adsorption energy. Strong electron transfer from SnO₂ to GQDs widens the electron depletion layer at SnO₂, thereby improving the gas response over a broad temperature range (RT–150 °C). This result provides a basic perspective for utilizing zero-dimensional GQDs in high-performance gas sensors operating over a wide range of temperatures.