Ba2B7O12F with novel FBB [B7O16F] and deep-ultraviolet cut-off edge

Zhaohong Miao; Yun Yang; Zhonglei Wei; Zhihua Yang; Shilie Pan

doi:10.1039/D0QI00924E

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Ba₂B₇O₁₂F with novel FBB [B₇O₁₆F] and deep-ultraviolet cut-off edge†

Zhaohong Miao,‡^ab Yun Yang,‡^a Zhonglei Wei,^ab Zhihua Yang

^a and Shilie Pan

*^a

Author affiliations

* Corresponding authors

^a CAS Key Laboratory of Functional Materials and Devices for Special Environments; Xinjiang Technical Institute of Physics & Chemistry, CAS; Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011, China
E-mail: slpan@ms.xjb.ac.cn

^b Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

A new member in the barium fluorooxoborate family, namely Ba₂B₇O₁₂F, was obtained by the high-temperature solution method in an open system under ambient pressure. The structure features a new fundamental building block [B₇O₁₆F], which interconnects with each other to form the anionic framework [B₇O₁₂F]_∞ with two different caves in which the cations reside. The experiment result indicates that Ba₂B₇O₁₂F possesses a deep-ultraviolet cut-off edge below 180 nm.

This article is part of the themed collection: 2020 Inorganic Chemistry Frontiers HOT articles

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Article information

DOI: https://doi.org/10.1039/D0QI00924E
Article type: Research Article
Submitted: 03 août 2020
Accepted: 29 oct. 2020
First published: 30 oct. 2020

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Inorg. Chem. Front., 2021,8, 339-343

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Ba₂B₇O₁₂F with novel FBB [B₇O₁₆F] and deep-ultraviolet cut-off edge

Z. Miao, Y. Yang, Z. Wei, Z. Yang and S. Pan, Inorg. Chem. Front., 2021, 8, 339 DOI: 10.1039/D0QI00924E

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