Issue 5, 2021

Activation of hydrogen peroxide by the nitrate anion in micellar media

Abstract

We present the activation of hydrogen peroxide by micellar imidazolium nitrates via H-bond formation in water, as shown by vibrational spectroscopy and supported by DFT calculations. Mechanistic insight into the interactions of the surfactant cation, the nitrate anion and H2O2 is given. The micelles solubilise and epoxidise cyclooctene in the aqueous phase.

Graphical abstract: Activation of hydrogen peroxide by the nitrate anion in micellar media

Supplementary files

Article information

Article type
Communication
Submitted
16 oct. 2020
Accepted
12 févr. 2021
First published
12 févr. 2021

Green Chem., 2021,23, 1965-1971

Activation of hydrogen peroxide by the nitrate anion in micellar media

F. Schmidt, B. Zehner, M. Kaposi, M. Drees, J. Mink, W. Korth, A. Jess and M. Cokoja, Green Chem., 2021, 23, 1965 DOI: 10.1039/D0GC03497E

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