Issue 27, 2020

Red-shifted backbone N–H photocaging agents

Abstract

Light is a uniquely powerful tool for spatiotemporal control of molecular structure, necessitating the development of new photocaging approaches. This communication describes the design, synthesis, and reactivity of two new photoreactive boronic acid reagents for backbone N–H modification and subsequent photocleavage.

Graphical abstract: Red-shifted backbone N–H photocaging agents

Supplementary files

Article information

Article type
Communication
Submitted
04 mai 2020
Accepted
30 mai 2020
First published
09 juin 2020

Org. Biomol. Chem., 2020,18, 5110-5114

Author version available

Red-shifted backbone N–H photocaging agents

A. E. Mangubat-Medina, H. O. Trial, R. D. Vargas, M. T. Setegne, T. Bader, M. D. Distefano and Z. T. Ball, Org. Biomol. Chem., 2020, 18, 5110 DOI: 10.1039/D0OB00923G

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