Aryl–Pd(II) chlorides stabilized by dialkylterphenyl phosphine ligands undergo a thermal isomerization process, leading to the formation of allyl–Pd(II)-chloride species. The transformation involves the intramolecular functionalization of a C–H bond of the terphenyl group mediated by the Pd(II) center.
R. J. Rama, C. Maya and M. C. Nicasio, Dalton Trans., 2019, 48, 14575 DOI: 10.1039/C9DT03201K
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