Issue 37, 2019

Pyridine–acetaldehyde, a molecular balance to explore the n→π* interaction

Abstract

The complex pyridine–acetaldehyde is formed through an n→π* interaction and a C–H⋯O contact. The acetaldehyde methyl group internal rotation induces a phase-locked intermolecular oscillation along the Bürgi–Dunitz coordinate. Surprisingly, this sort of molecular balance extracts energy through the n→π* interaction to reduce the size of the internal rotation barrier.

Graphical abstract: Pyridine–acetaldehyde, a molecular balance to explore the n→π* interaction

Supplementary files

Article information

Article type
Communication
Submitted
22 juil. 2019
Accepted
06 sept. 2019
First published
06 sept. 2019

Phys. Chem. Chem. Phys., 2019,21, 20566-20570

Pyridine–acetaldehyde, a molecular balance to explore the n→π* interaction

S. Blanco, A. Macario and J. C. López, Phys. Chem. Chem. Phys., 2019, 21, 20566 DOI: 10.1039/C9CP04088A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements