Issue 16, 2019
From the journal:

Chemical Communications

Halogen bonding effects on the outcome of reactions at metal centres†‡

Lucas Carreras, ORCID logo a   Jordi Benet-Buchholz,a   Antonio Franconetti, ORCID logo b   Antonio Frontera, ORCID logo b   Piet W. N. M. van Leeuwen ORCID logo c  and  Anton Vidal-Ferran ORCID logo *ad  

* Corresponding authors

a Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology, Av. Països Catalans 16, Tarragona 43007, Spain
E-mail: avidal@iciq.cat

b Departament de Química, Universitat de les Illes Balears (UIB), Ctra. de Valldemossa km 7.5, 07122 Palma de Mallorca, Spain

c LPCNO, INSA-Toulouse, 135 Avenue de Rangueil, F-31077 Toulouse, France

d ICREA, Pg. Lluís Companys 23, 08010 Barcelona, Spain

Abstract

Key findings regarding the effects of ligand preorganisation via halogen bonding on the outcome of reactions at rhodium are reported. An unprecedented halogen bonding-mediated oxidative addition of CAr–I bonds to rhodium with efficient formation of cyclometallated species deserves special mention.

Graphical abstract: Halogen bonding effects on the outcome of reactions at metal centres

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Article information

DOI
https://doi.org/10.1039/C8CC08884E
Article type
Communication
Submitted
07 nov. 2018
Accepted
30 janv. 2019
First published
31 janv. 2019

Chem. Commun., 2019,55, 2380-2383

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Halogen bonding effects on the outcome of reactions at metal centres

L. Carreras, J. Benet-Buchholz, A. Franconetti, A. Frontera, P. W. N. M. van Leeuwen and A. Vidal-Ferran, Chem. Commun., 2019, 55, 2380 DOI: 10.1039/C8CC08884E

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