Issue 33, 2018

Synthesis of 2,2-difluoro-homoallylic alcohols via ring-opening of gem-difluorocyclopropane and aerobic oxidation by photo-irradiation in the presence of an organic pigment

Abstract

We found that aerobic oxidation took place after the visible light-mediated ring-opening reaction of gem-difluorocyclopropane in the presence of an organic dye and amine to furnish 2,2-difluoro-homoallylic alcohols in good yields.

Graphical abstract: Synthesis of 2,2-difluoro-homoallylic alcohols via ring-opening of gem-difluorocyclopropane and aerobic oxidation by photo-irradiation in the presence of an organic pigment

Supplementary files

Article information

Article type
Paper
Submitted
20 juil. 2018
Accepted
06 août 2018
First published
06 août 2018

Org. Biomol. Chem., 2018,16, 6106-6114

Synthesis of 2,2-difluoro-homoallylic alcohols via ring-opening of gem-difluorocyclopropane and aerobic oxidation by photo-irradiation in the presence of an organic pigment

H. Takenaka, Y. Masuhara, K. Narita, T. Nokami and T. Itoh, Org. Biomol. Chem., 2018, 16, 6106 DOI: 10.1039/C8OB01740A

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