Issue 1, 2018

Designing high performance all-small-molecule solar cells with non-fullerene acceptors: comprehensive studies on photoexcitation dynamics and charge separation kinetics

Abstract

Solution-processable all-small-molecule organic solar cells (OSCs) have shown dramatic progress in improving stability and photovoltaic efficiency. However, knowledge of photoexcitation dynamics in this novel class of materials is very limited. To fully exploit the design capacities inherent in small molecule chemistry, the elementary processes and branching yields must be known in detail. Here, we present a combined computational–experimental study of photoexcitation dynamics of a prototypical all-small-molecule photovoltaic blend, p-DTS(FBTTh2)2 as a donor and NIDCS-MO as an acceptor. Femtosecond spectroscopy data show that excitonic coupling is small and that the charge transfer states are localized, at first glance contradicting the high internal quantum efficiency (IQE) and open circuit voltage (VOC) of this material. A target analysis of the femtosecond spectra yields exciton dissociation rates of 1/(25 ps) and 1/(100 ps) for the as-deposited and annealed blend, respectively. These rates are far slower than in typical polymer based organic solar cells. Still, internal quantum yields are high because parasitic quenching processes are found to be even slower. In the framework of semiclassical Marcus theory, we demonstrate that our system shows near-optimum energy conversion and charge separation yields, due to negligible activation energy for charge generation but high activation energy for charge recombination, allowing enough time to separate localized charge transfer states. We thus justify both the high internal quantum yields and the high open circuit voltage found in this system. Finally, we predict that highly efficient and stable low-optical bandgap systems can be realized by reducing the electronic coupling between the donor and acceptor.

Graphical abstract: Designing high performance all-small-molecule solar cells with non-fullerene acceptors: comprehensive studies on photoexcitation dynamics and charge separation kinetics

Supplementary files

Article information

Article type
Paper
Submitted
16 oct. 2017
Accepted
12 déc. 2017
First published
12 déc. 2017

Energy Environ. Sci., 2018,11, 211-220

Designing high performance all-small-molecule solar cells with non-fullerene acceptors: comprehensive studies on photoexcitation dynamics and charge separation kinetics

J. Shi, A. Isakova, A. Abudulimu, M. van den Berg, O. K. Kwon, A. J. Meixner, S. Y. Park, D. Zhang, J. Gierschner and L. Lüer, Energy Environ. Sci., 2018, 11, 211 DOI: 10.1039/C7EE02967E

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