Issue 40, 2018

Dual emissions and thermochromic luminescences of isomorphic chiral twofold interpenetrated 3-D nets built from I1O2 type hybrid inorganic–organic frameworks of [NH2(CH3)2]3[Pb2X3(BDC)2] (X = Br, I)

Abstract

Two pairs of MOF-based hybrid enantiomorphs, [NH2(CH3)2]3[Pb2X3(BDC)2] (H2BDC = 1,4-benzenedicarboxylic acid, X = Br or I), have been synthesized using the solvothermal reaction and then manually separated, which are labeled as 1a/1b (X = Br) and 2a/2b (X = I). The isomorphic 1a and 2a crystallize in tetragonal space group P43212, and the isomorphic 1b and 2b in the enantiomorphic space group P41212. Twofold interpenetrated three-dimensional (3-D) networks were built from two sets of equivalent I1O2 type hybrid inorganic–organic frameworks in 1a/1b and 2a/2b. Each I1O2 type hybrid inorganic–organic framework constructs by the inorganic pentagonal bipyramid-shape PbX3O4 (X = Br or I) polyhedral chains along the c-axis, which are further connected though bridged BDC2− ligands in the directions perpendicular to the c-axis. Hybrids 1a/1b and 2a/2b have been characterized by elemental analysis (C, H and N elements), thermogravimetric and powder X-ray diffraction techniques, and UV-visible absorption spectroscopy in the solid state. These hybrids show dual emissions at ambient conditions, which arise from the π–π* electron transition within the aromatic rings in the BDC2− ligands and the electron transition in the inorganic polyhedral semiconducting chains, as well as thermochromic luminescence behavior from 10 to 300 K owing to two emission bands displaying different responses to the temperature change.

Graphical abstract: Dual emissions and thermochromic luminescences of isomorphic chiral twofold interpenetrated 3-D nets built from I1O2 type hybrid inorganic–organic frameworks of [NH2(CH3)2]3[Pb2X3(BDC)2] (X = Br, I)

Supplementary files

Article information

Article type
Paper
Submitted
14 avr. 2018
Accepted
08 mai 2018
First published
09 mai 2018

Dalton Trans., 2018,47, 14233-14240

Dual emissions and thermochromic luminescences of isomorphic chiral twofold interpenetrated 3-D nets built from I1O2 type hybrid inorganic–organic frameworks of [NH2(CH3)2]3[Pb2X3(BDC)2] (X = Br, I)

S. Liu, G. Yuan, L. Zhai, L. Wang, H. Luo and X. Ren, Dalton Trans., 2018, 47, 14233 DOI: 10.1039/C8DT01469H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements