Issue 27, 2018

Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand

Abstract

A neutral heterobimetallic triple-decker stannole complex was prepared by the reaction of an anionic ruthenocene bearing a stannole dianionic ligand with [Rh(cod)Cl]2 (cod = 1,5-cyclooctadiene), and the resulting Ru–Rh complex exhibits an electronic property different from those of the corresponding Ru–Ru and Rh–Rh complexes. The Ru–Rh complex can be decomposed in ionic liquids to metal nanoparticles.

Graphical abstract: Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand

Supplementary files

Article information

Article type
Paper
Submitted
13 avr. 2018
Accepted
07 mai 2018
First published
10 mai 2018

Dalton Trans., 2018,47, 8892-8896

Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand

M. Saito, N. Matsunaga, J. Hamada, S. Furukawa, M. Minoura, S. Wegner, J. Barthel and C. Janiak, Dalton Trans., 2018, 47, 8892 DOI: 10.1039/C8DT01455H

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