Issue 17, 2016
From the journal:

Journal of Materials Chemistry A

Covalent triazine-based frameworks (CTFs) from triptycene and fluorene motifs for CO2 adsorption†

Subarna Dey,a   Asamanjoy Bhunia,a   Dolores Esquivelb  and  Christoph Janiak*a  

* Corresponding authors

a Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine-Universität Düsseldorf, 40204 Düsseldorf, Germany
E-mail: janiak@uni-duesseldorf.de

b Department of Organic Chemistry, Nanochemistry and Fine Chemistry Research Institute (IUIQFN), Faculty of Sciences, University of Córdoba, Campus de Rabanales, Marie Curie Building, Ctra. Nnal. IV, 14071 Córdoba, Spain

Abstract

Two microporous covalent triazine-based frameworks (CTFs) with triptycene (TPC) and fluorene (FL) backbones have been synthesized through a mild AlCl3-catalyzed Friedel–Crafts reaction, with the highest surface area of up to 1668 m2 g−1 for non-ionothermal CTFs. CTF-TPC and CTF-FL show an excellent carbon dioxide uptake capacity of up to 4.24 mmol g−1 at 273 K and 1 bar.

Graphical abstract: Covalent triazine-based frameworks (CTFs) from triptycene and fluorene motifs for CO2 adsorption

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Article information

DOI
https://doi.org/10.1039/C6TA00638H
Article type
Communication
Submitted
22 janv. 2016
Accepted
30 mars 2016
First published
31 mars 2016
This article is Open Access
Creative Commons BY-NC license

J. Mater. Chem. A, 2016,4, 6259-6263

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Covalent triazine-based frameworks (CTFs) from triptycene and fluorene motifs for CO2 adsorption

S. Dey, A. Bhunia, D. Esquivel and C. Janiak, J. Mater. Chem. A, 2016, 4, 6259 DOI: 10.1039/C6TA00638H

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