Issue 21, 2016

Aminal linked inorganic–organic hybrid nanoporous materials (HNMs) for CO2 capture and H2 storage applications

Abstract

Nitrogen-rich aminal linked inorganic–organic hybrid nanoporous materials (HNMs) with cyclophosphazene moieties in the frameworks were synthesized by a Schiff base condensation reaction. The ultra-microporous materials have a specific surface area (SBET) upto 976 m2 g−1 and could capture 18.9 wt% CO2 and 1.6 wt% H2 at 273 and 77 K, respectively, at 1 bar. The materials have a nitrogen content upto 42% which is the highest among the nanoporous materials category. The high nitrogen content is beneficial for several applications such as CO2 capture.

Graphical abstract: Aminal linked inorganic–organic hybrid nanoporous materials (HNMs) for CO2 capture and H2 storage applications

Supplementary files

Article information

Article type
Paper
Submitted
05 déc. 2015
Accepted
01 févr. 2016
First published
02 févr. 2016

RSC Adv., 2016,6, 17100-17105

Aminal linked inorganic–organic hybrid nanoporous materials (HNMs) for CO2 capture and H2 storage applications

R. Muhammad, P. Rekha and P. Mohanty, RSC Adv., 2016, 6, 17100 DOI: 10.1039/C5RA25933A

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