Issue 58, 2016
From the journal:

Chemical Communications

Selective partial hydrogenation of alkynes to (Z)-alkenes with ionic liquid-doped nickel nanocatalysts at near ambient conditions†

Hannelore Konnertha  and  Martin H. G. Prechtl*a  

* Corresponding authors

a Department of Chemistry, Institute of Inorganic Chemistry, University of Cologne, Greinstraße 6, 50939 Cologne, Germany
E-mail: martin.prechtl@uni-koeln.de
Web: http://catalysis.uni-koeln.de
Fax: +49 221 4701788

Abstract

A selective hydrogenation method for forming (Z)-alkenes from alkynes has been developed using a catalyst system of cheap Ni-NPs in a nitrile functionalised imidazolium based ionic liquid (IL) operating under very mild reaction conditions of 30–50 °C and 1–4 bar H2 pressure.

Graphical abstract: Selective partial hydrogenation of alkynes to (Z)-alkenes with ionic liquid-doped nickel nanocatalysts at near ambient conditions

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Article information

DOI
https://doi.org/10.1039/C6CC00499G
Article type
Communication
Submitted
18 janv. 2016
Accepted
24 mars 2016
First published
29 mars 2016
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2016,52, 9129-9132

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Selective partial hydrogenation of alkynes to (Z)-alkenes with ionic liquid-doped nickel nanocatalysts at near ambient conditions

H. Konnerth and M. H. G. Prechtl, Chem. Commun., 2016, 52, 9129 DOI: 10.1039/C6CC00499G

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