Issue 2, 2015
From the journal:

Organic Chemistry Frontiers

Difluoromethyl 2-pyridyl sulfone: a versatile carbonyl gem-difluoroolefination reagent

Bing Gao,a   Yanchuan Zhao,a   Jingyu Hua  and  Jinbo Hu*a  

* Corresponding authors

a Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China
E-mail: jinbohu@sioc.ac.cn

Abstract

This tutorial account describes a robust carbonyl gem-difluoroolefination reagent, difluoromethyl 2-pyridyl sulfone (2-PySO2CF2H), developed by our group, recently. The guidelines for its laboratory preparation and application are presented in detail for potential users.

Graphical abstract: Difluoromethyl 2-pyridyl sulfone: a versatile carbonyl gem-difluoroolefination reagent

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Article information

DOI
https://doi.org/10.1039/C4QO00291A
Article type
Tutorial Account
Submitted
06 nov. 2014
Accepted
12 déc. 2014
First published
16 déc. 2014

Org. Chem. Front., 2015,2, 163-168

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Difluoromethyl 2-pyridyl sulfone: a versatile carbonyl gem-difluoroolefination reagent

B. Gao, Y. Zhao, J. Hu and J. Hu, Org. Chem. Front., 2015, 2, 163 DOI: 10.1039/C4QO00291A

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