AFM study of oxygen reduction products on HOPG in the LiPF6–DMSO electrolyte

Abstract

Ex situ atomic force microscopy (AFM) has been used to study the morphology of oxygen reduction products in the LiPF₆–dimethyl sulfoxide (DMSO) electrolyte, i.e. Li₂O₂ on a highly oriented pyrolytic graphite (HOPG) surface. Both cyclic voltammetry and chronoamperometry have shown that at low cathodic polarization the initial deposits decorate the edge steps of HOPG. At higher overpotentials a massive deposit covers the terraces. Upon charging the battery cathode Li₂O₂ oxidation and dissolution do not take place until high overpotentials are reached at which solvent decomposition has been demonstrated by in situ FTIR studies.