Issue 39, 2013
From the journal:

Chemical Communications

Reactions of a tungsten–germylyne complex with alcohols and arylaldehydes†‡

Tetsuya Fukuda,a   Hisako Hashimoto*a  and  Hiromi Tobita*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Tohoku University, Aoba-ku, Sendai, Japan
E-mail: hhashimoto@m.tohoku.ac.jp, tobita@m.tohoku.ac.jp
Fax: +81 22 795 6543
Tel: +81 22 795 6540

Abstract

A germylyne complex Cp*(CO)2W[triple bond, length as m-dash]GeC(SiMe3)3 (1) reacted with alcohols to give simple nucleophilic addition products, while 1 reacted with two molecules of arylaldehydes consecutively to give base-stabilised alkoxy(germylene) complexes via C–H bond activation and hydrogermylation.

Graphical abstract: Reactions of a tungsten–germylyne complex with alcohols and arylaldehydes

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Article information

DOI
https://doi.org/10.1039/C2CC37126J
Article type
Communication
Submitted
01 oct. 2012
Accepted
01 nov. 2012
First published
02 nov. 2012

Chem. Commun., 2013,49, 4232-4234

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Reactions of a tungsten–germylyne complex with alcohols and arylaldehydes

T. Fukuda, H. Hashimoto and H. Tobita, Chem. Commun., 2013, 49, 4232 DOI: 10.1039/C2CC37126J

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