Dynamic HPLC study of C70 chlorination reveals a surprisingly selective synthesis of C70Cl8

Igor V. Kuvychko; Alexey A. Popov; Alexey V. Streletskii; Leanne C. Nye; Thomas Drewello; Steven H. Strauss; Olga V. Boltalina

doi:10.1039/C0CC03134H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Dynamic HPLC study of C₇₀chlorination reveals a surprisingly selective synthesis of C₇₀Cl₈†‡

Igor V. Kuvychko,^a Alexey A. Popov,^b Alexey V. Streletskii,^c Leanne C. Nye,§^c Thomas Drewello,§^c Steven H. Strauss*^a and Olga V. Boltalina*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA
E-mail: steven.strauss@colostate.edu, olga.boltalina@colostate.edu
Fax: +1 970-491-1801
Tel: +1 970-491-5088

^b Leibniz Institute for Solid State and Materials Research Dresden, Helmholtzstrasse 20, Dresden D01069, Germany

^c Warwick University, Coventry CV4 7AL, UK

Abstract

A dynamic HPLC study of C₇₀ chlorination led to the discovery, isolation, characterization, and development of the efficient preparatory procedures for two previously unknown soluble chlorofullerenes C₇₀Cl₈ and C₇₀Cl₆ and for insoluble [C₇₀Cl₈]_n. A novel synthesis of 99% pure C₇₀Cl₁₀ with a nearly quantitative yield was also developed. The first stability study of C₇₀Cl_10,8,6 in solution showed that these compounds are very light-sensitive.

This article is part of the themed collection: Carbon nanostructures

Download options Please wait...

Supplementary files

Experimental details, literature data on C ₇₀ chlorination, and additional figures PDF (2166K)

Article information

DOI: https://doi.org/10.1039/C0CC03134H
Article type: Communication
Submitted: 09 août 2010
Accepted: 03 sept. 2010
First published: 27 sept. 2010

Download Citation

Chem. Commun., 2010,46, 8204-8206

Permissions

Request permissions

Dynamic HPLC study of C₇₀ chlorination reveals a surprisingly selective synthesis of C₇₀Cl₈

I. V. Kuvychko, A. A. Popov, A. V. Streletskii, L. C. Nye, T. Drewello, S. H. Strauss and O. V. Boltalina, Chem. Commun., 2010, 46, 8204 DOI: 10.1039/C0CC03134H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications