Issue 32, 2007

Telluroselenophosphonium ions: their unusual soft–soft interactions with iodotellurate anions

Abstract

Formally uncharged two-coordinate tellurium atoms in trialkyl(telluroseleno)phosphonium salts [(tBu2iPrPSeTe-p-Tol)+ (p-TolTeI2)] (2a) and {[(iPr3PSeTeI)+]2 (TeI6)2−} (5) behave as soft acceptors towards iodotellurate anions, thus exhibiting a novel type of Te⋯Te anion → cation donor–acceptor interaction (2a) and a chelating TeIV(µ-I)2TeII anion–cation coordination (5) in the solid state.

Graphical abstract: Telluroselenophosphonium ions: their unusual soft–soft interactions with iodotellurate anions

Supplementary files

Article information

Article type
Communication
Submitted
01 juin 2007
Accepted
06 juin 2007
First published
28 juin 2007

Dalton Trans., 2007, 3483-3485

Telluroselenophosphonium ions: their unusual soft–soft interactions with iodotellurate anions

C. G. Hrib, J. Jeske, P. G. Jones and Wolf-W. du Mont, Dalton Trans., 2007, 3483 DOI: 10.1039/B708370J

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