Issue 4, 2023

Diverse CsPbI3 assembly structures: the role of surface acids

Abstract

Surface ligand engineering, seed introduction and external driving forces play major roles in controlling the anisotropic growth of halide perovskites, which have been widely established in CsPbBr3 nanomaterials. However, colloidal CsPbI3 nanocrystals (NCs) have been less studied due to their low formation energy and low electronegativity. Here, by introducing different molar ratios of surface acids and amines to limit the monomer concentration of lead–iodine octahedra during nucleation, we report dumbbell-shaped CsPbI3 NCs obtained by the in situ self-assembly of nanospheres and nanorods with average sizes of 89 nm and 325 nm, respectively, which showed a high photoluminescence quantum yield of 89%. Structural and surface state analyses revealed that the strong binding of benzenesulfonic acid promoted the formation of a Pb(SO3)x-rich surface of CsPbI3 assembly structures. Furthermore, the addition of benzenesulfonic acid increases the supersaturation threshold and the solubility of PbI2 in a high-temperature reaction system, and controls effectively the lead–iodine octahedron monomer concentration in the second nucleation stage. As a result, the as-synthesized CsPbI3-Sn NCs exhibited different assembly morphologies and high PLQYs, among which the role of sulfonate groups can be further verified by UV absorption and surface characteristics. The strategy provides a new frontier to rationally control the surface ligand-induced self-assembly structures of perovskites.

Graphical abstract: Diverse CsPbI3 assembly structures: the role of surface acids

Supplementary files

Article information

Article type
Paper
Submitted
06 nov. 2022
Accepted
13 déc. 2022
First published
13 déc. 2022

Nanoscale, 2023,15, 1637-1644

Diverse CsPbI3 assembly structures: the role of surface acids

D. Yang, X. Zhang, S. Liu, Z. Xu, Y. Yang, X. Li, Q. Ye, Q. Xu and H. Zeng, Nanoscale, 2023, 15, 1637 DOI: 10.1039/D2NR06208A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements