Issue 43, 2021

An evaluation of palladium-based catalysts for the base-free borylation of alkenyl carboxylates

Abstract

Synthesis of organoboron derivatives is a key application of catalytic cross-coupling, with the Pd-catalyzed Miyaura borylation among the most versatile methods available. We have evaluated several Pd-based systems for borylation of alkenyl acetates and pivalates, with the optimal system heavily dependant on the substrate structure.

Graphical abstract: An evaluation of palladium-based catalysts for the base-free borylation of alkenyl carboxylates

Supplementary files

Article information

Article type
Communication
Submitted
25 août 2021
Accepted
04 oct. 2021
First published
04 oct. 2021

New J. Chem., 2021,45, 20095-20098

An evaluation of palladium-based catalysts for the base-free borylation of alkenyl carboxylates

G. Gaube, N. Pipaon Fernandez and D. C. Leitch, New J. Chem., 2021, 45, 20095 DOI: 10.1039/D1NJ04008A

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