Issue 20, 2021

Positive thermal expansion facilitates the formation of argentophilic forces following an order–disorder phase transition

Abstract

Argentophilic forces are formed in a coordination complex based on silver(I) trifluoromethanesulfonate and 4-stilbazole as a ligand. The forces are absent at low temperature and form as a result of an order–disorder phase transition that occurs upon heating. Colossal positive thermal expansion also precedes the phase transition.

Graphical abstract: Positive thermal expansion facilitates the formation of argentophilic forces following an order–disorder phase transition

Supplementary files

Article information

Article type
Communication
Submitted
19 janv. 2021
Accepted
30 avr. 2021
First published
03 mai 2021

New J. Chem., 2021,45, 8898-8901

Positive thermal expansion facilitates the formation of argentophilic forces following an order–disorder phase transition

N. Juneja, D. K. Unruh, R. H. Groeneman and K. M. Hutchins, New J. Chem., 2021, 45, 8898 DOI: 10.1039/D1NJ00312G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements