Enantioselective recognition of chiral acids by supramolecular interactions with chiral AIEgens

Song Xiang; Panpan Lv; Changsheng Guo; Chunxuan Qi; Jun-Cheng Yang; Jingjing Tian; De-Suo Yang; Hai-Tao Feng; Ben Zhong Tang

doi:10.1039/D1CC05618B

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Enantioselective recognition of chiral acids by supramolecular interactions with chiral AIEgens†

Song Xiang,^a Panpan Lv,^a Changsheng Guo,^a Chunxuan Qi,^a Jun-Cheng Yang,^a Jingjing Tian,^a De-Suo Yang,*^a Hai-Tao Feng

*^a and Ben Zhong Tang

*^b

Author affiliations

* Corresponding authors

^a AIE Research Center, Shaanxi Key Laboratory of Phytochemistry, College of Chemistry and Chemical Engineering, Baoji University of Arts and Sciences, Baoji 721013, China
E-mail: haitaofeng907@163.com

^b Shenzhen Institute of Aggregate Science and Technology, School of Science and Engineering, The Chinese University of Hong Kong, Shenzhen, Guangdong 518172, China
E-mail: tangbenz@ust.hk

Abstract

Novel chiral AIEgens bearing optically pure amino groups were synthesized and showed excellent discrimination for a series of chiral acidic compounds and amino acids. Interestingly, after supramolecular assembly with 4-sulfocalix[4]arene, the obtained complexes showed enhanced enantioselectivity for chiral acids.

This article is part of the themed collection: Functional Supramolecular Photochemistry

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Article information

DOI: https://doi.org/10.1039/D1CC05618B
Article type: Communication
Submitted: 05 oct. 2021
Accepted: 15 nov. 2021
First published: 17 nov. 2021

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Chem. Commun., 2021,57, 13321-13324

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Enantioselective recognition of chiral acids by supramolecular interactions with chiral AIEgens

S. Xiang, P. Lv, C. Guo, C. Qi, J. Yang, J. Tian, D. Yang, H. Feng and B. Z. Tang, Chem. Commun., 2021, 57, 13321 DOI: 10.1039/D1CC05618B

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Chemical Communications

Enantioselective recognition of chiral acids by supramolecular interactions with chiral AIEgens†

Abstract

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Enantioselective recognition of chiral acids by supramolecular interactions with chiral AIEgens

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