Issue 11, 2019

Highly luminescent red emissive perovskite quantum dots-embedded composite films: ligands capping and caesium doping-controlled crystallization process

Abstract

Perovskite quantum dots (PQDs) are emerging as functional luminescence down-shifting materials for light conversion applications. The incorporation of PQDs into a polymeric matrix is a key step to improving their stability, thus facilitating device integration. Compared to the conventional way of mixing the pre-synthesized PQDs into a polymer, the in situ fabrication of perovskite quantum dots-embedded composite films (PQDCFs) is an efficient and cost-effective method, which yields enhanced photoluminescence properties. This method has been successfully developed for green emissive CH3NH3PbBr3 PQDCFs, whereas the red CH3NH3PbI3 PQDCFs only show the photoluminescence quantum yields (PLQYs) less than 15%. By means of combining transmittance electron microscopy (TEM) and absorption spectrum analysis, we showed that the “perovskite red wall” in PQDCFs was mainly related to the phase separation, formation of large-sized particles and incomplete chemical conversion of precursors. These problems are caused by the solubility variance of perovskite precursors in the solvent as well as the solvation compatibility between perovskite precursors and the polymer during the crystallization process. Based on these findings, we introduced Cs+ as a dopant and 3,3-diphenylpropyamine (DPPA) as capping ligands, respectively, to decrease the solubility variance of the precursors and improve the compatibility between PQDs and the polymer. Consequently, highly luminescent red emissive PQDCFs with a PLQY of 91% were achieved with this strategy.

Graphical abstract: Highly luminescent red emissive perovskite quantum dots-embedded composite films: ligands capping and caesium doping-controlled crystallization process

Supplementary files

Article information

Article type
Paper
Submitted
12 déc. 2018
Accepted
16 févr. 2019
First published
18 févr. 2019

Nanoscale, 2019,11, 4942-4947

Highly luminescent red emissive perovskite quantum dots-embedded composite films: ligands capping and caesium doping-controlled crystallization process

X. Wu, J. Tang, F. Jiang, X. Zhu, Y. Zhang, D. Han, L. Wang and H. Zhong, Nanoscale, 2019, 11, 4942 DOI: 10.1039/C8NR10036E

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