Issue 44, 2019
From the journal:

Chemical Communications

Shape-persistent pyrrole-based covalent organic cages: synthesis, structure and selective gas adsorption properties†‡

Fei Wang,ab   Eric Sikma,c   Zhiming Duan, ORCID logo b   Tridib Sarma, ORCID logo b   Chuanhu Lei,b   Zhan Zhang, ORCID logo *bd   Simon M. Humphrey ORCID logo *c  and  Jonathan L. Sessler ORCID logo *bc  

* Corresponding authors

a School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China

b Center for Supramolecular Chemistry & Catalysis, Shanghai University, Shanghai 200444, China
E-mail: zhangzhan5@foxmail.com

c Department of Chemistry, The University of Texas at Austin, Texas 78712-1224, USA
E-mail: smh@cm.utexas.edu, sessler@cm.utexas.edu

d College of Chemistry and Material Sciences, South-Central University for Nationalities, Wuhan, Hubei 430074, China

Abstract

Two cryptand-like, shape persistent [2+3] imine cages (1 and 2) derived from oligopyrrolic precursors (diformyl dipyrrylpyridine 3 and diformyl bipyrrole 4) were prepared. These cages contain open cavities as inferred from solid state structural analyses and act as selective CO2 gas adsorbing materials in the solid state.

Graphical abstract: Shape-persistent pyrrole-based covalent organic cages: synthesis, structure and selective gas adsorption properties

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Article information

DOI
https://doi.org/10.1039/C9CC02490E
Article type
Communication
Submitted
30 mars 2019
Accepted
08 avr. 2019
First published
13 mai 2019

Chem. Commun., 2019,55, 6185-6188

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Shape-persistent pyrrole-based covalent organic cages: synthesis, structure and selective gas adsorption properties

F. Wang, E. Sikma, Z. Duan, T. Sarma, C. Lei, Z. Zhang, S. M. Humphrey and J. L. Sessler, Chem. Commun., 2019, 55, 6185 DOI: 10.1039/C9CC02490E

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