Issue 58, 2016
From the journal:

Chemical Communications

Radical C–H arylations of (hetero)arenes catalysed by gallic acid†

Marcelle D. Perretti,‡a   Diego M. Monzón,‡a   Fernando P. Crisóstomo,a   Víctor S. Martína  and  Romen Carrillo*a  

* Corresponding authors

a Departamento de Química Orgánica, Instituto Universitario de Bio-Orgánica “Antonio González” (IUBO), Centro de Investigaciones Biomédicas de Canarias (CIBICAN), Universidad de La Laguna. Avda. Astrofísico Fco. Sánchez 2, Apdo. Correos 456, 38200 – La Laguna, S/C. de Tenerife, Spain
E-mail: rocarril@ull.es
Tel: +34 922 318 583

Abstract

Gallic acid efficiently catalyses radical arylations in water–acetone at room temperature. This methodology proved to be versatile and scalable. Therefore, it constitutes a greener alternative to arylation. Moreover, considering that gallic acid is an abundant vegetable tannin, this work also unleashes an alternative method for the reutilisation of bio-wastes.

Graphical abstract: Radical C–H arylations of (hetero)arenes catalysed by gallic acid

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Article information

DOI
https://doi.org/10.1039/C5CC09911K
Article type
Communication
Submitted
01 déc. 2015
Accepted
15 janv. 2016
First published
15 janv. 2016

Chem. Commun., 2016,52, 9036-9039

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Radical C–H arylations of (hetero)arenes catalysed by gallic acid

M. D. Perretti, D. M. Monzón, F. P. Crisóstomo, V. S. Martín and R. Carrillo, Chem. Commun., 2016, 52, 9036 DOI: 10.1039/C5CC09911K

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