One-dimensional water cages with repeat units of (H2O)24 resembling pagodane trapped in a 3D coordination polymer: proton conduction and tunable luminescence emission by adsorption of anionic dyes

Kartik Maity; Tanay Kundu; Rahul Banerjee; Kumar Biradha

doi:10.1039/C5CE00969C

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

One-dimensional water cages with repeat units of (H₂O)₂₄ resembling pagodane trapped in a 3D coordination polymer: proton conduction and tunable luminescence emission by adsorption of anionic dyes†

Kartik Maity,^a Tanay Kundu,^b Rahul Banerjee^b and Kumar Biradha*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Indian Institute of Technology, Kharagpur-721302, India
E-mail: kbiradha@chem.iitkgp.ernet.in
Tel: +91 3222 283346

^b Physical/Materials Chemistry Division, CSIR National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411008, India

Abstract

A 3D-coordination polymer was shown to trap one-dimensional polyhedral water cages consisting of repeat units of (H₂O)₂₄, the geometry of which resembles the exotic organic molecule pagodane. Further, this material exhibited proton conduction ability and tunable luminescence emission by adsorption of anionic dyes such as the fluorescein dianion.

This article is part of the themed collection: Introducing the CrystEngComm Advisory Board and their research

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C5CE00969C
Article type: Communication
Submitted: 09 avr. 2015
Accepted: 22 mai 2015
First published: 25 mai 2015

Download Citation

CrystEngComm, 2015,17, 4439-4443

Permissions

Request permissions

One-dimensional water cages with repeat units of (H₂O)₂₄ resembling pagodane trapped in a 3D coordination polymer: proton conduction and tunable luminescence emission by adsorption of anionic dyes

K. Maity, T. Kundu, R. Banerjee and K. Biradha, CrystEngComm, 2015, 17, 4439 DOI: 10.1039/C5CE00969C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

CrystEngComm