Issue 2, 2014
From the journal:

Chemical Science

Aggregation-induced emission enhancement of a meso-trifluoromethyl BODIPY via J-aggregation†

Sohee Choi,a   Jean Bouffardb  and  Youngmi Kim*a  

* Corresponding authors

a Department of Chemistry, Institute of Nanosensor and Biotechnology, Dankook University, 126 Jukjeon-dong, Yongin-si, Gyeonggi-do, Korea
E-mail: youngmi@dankook.ac.kr
Fax: +82 31 8005 3148
Tel: +82 31 8005 3156

b Department of Chemistry and Nano Science, and Global Top5 Research Program, Ewha Womans University, 52 Ewhayeodae-gil, Seodaemun-gu, Seoul 120-750, Korea

Abstract

A CF3-BODIPY forms strongly luminescent aggregates, which contrasts with the quenched condensed-phase photophysics that are typical for BODIPY dyes. Examination of the luminescent properties of these aggregates – narrow red-shifted absorption and emission bands, minimal Stokes shift and increased fluorescence rate constants – and of the solid-state packing of the dye establish the CF3-BODIPY as the first structurally characterized genuine BODIPY J-aggregate.

Graphical abstract: Aggregation-induced emission enhancement of a meso-trifluoromethyl BODIPY via J-aggregation

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Article information

DOI
https://doi.org/10.1039/C3SC52495G
Article type
Edge Article
Submitted
05 sept. 2013
Accepted
24 oct. 2013
First published
25 oct. 2013

Chem. Sci., 2014,5, 751-755

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Aggregation-induced emission enhancement of a meso-trifluoromethyl BODIPY via J-aggregation

S. Choi, J. Bouffard and Y. Kim, Chem. Sci., 2014, 5, 751 DOI: 10.1039/C3SC52495G

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