Issue 26, 2011
From the journal:

Chemical Communications

Luminescence enhancement and tuning via multiple cooperative supramolecular interactions in an ion-paired multinuclear complex†

Chi Yang,a   Oussama Elbjeirami,‡a   Chammi S. Palehepitiya Gamage,b   H. V. Rasika Diasb  and  Mohammad A. Omary*a  

* Corresponding authors

a Department of Chemistry, University of North Texas, Denton, Texas 76203, USA
E-mail: omary@unt.edu

b Department of Chemistry and Biochemistry, The University of Texas at Arlington, Arlington, Texas 76019, USA
E-mail: dias@uta.edu

Abstract

[(3,5-(CF3)2Pz)(AgL)2]+[Ag5(3,5-(CF3)2Pz)6(CH3CN)]− (L = 2-(N,N-diethylanilino-4-yl)-4,6-bis(3,5-dimethylpyrazol-1-yl)-1,3,5-triazine) shows bright and tunable emissions influenced by its supramolecular structure. Columnar stacks are assembled via cooperative interactions that include AgI⋯AgI argentophilic bonding, π⋯π stacking and AgI⋯π interactions.

Graphical abstract: Luminescence enhancement and tuning via multiple cooperative supramolecular interactions in an ion-paired multinuclear complex

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Article information

DOI
https://doi.org/10.1039/C1CC11161B
Article type
Communication
Submitted
26 févr. 2011
Accepted
11 avr. 2011
First published
01 juin 2011

Chem. Commun., 2011,47, 7434-7436

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Luminescence enhancement and tuning via multiple cooperative supramolecular interactions in an ion-paired multinuclear complex

C. Yang, O. Elbjeirami, C. S. P. Gamage, H. V. R. Dias and M. A. Omary, Chem. Commun., 2011, 47, 7434 DOI: 10.1039/C1CC11161B

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