Issue 27, 2010
From the journal:

Dalton Transactions

Thermal reaction of a (hydrido)(selenolato)platinum(ii) complex having a dibenzobarrelenylgroup leading to three cyclometalations†

Akihiko Ishii,*a   Yuki Yamaguchia  and  Norio Nakataa  

* Corresponding authors

a Department of Chemistry, Graduate School of Science and Engineering, Saitama University, Shimo-okubo 255, Sakura-ku, Saitama, Japan
E-mail: ishiiaki@chem.saitama-u.ac.jp
Fax: +81-48-858-3394

Abstract

The thermal reaction of a (dibenzobarreleneselenolato)(hydrido)platinum(II) complex gave two four-membered selenaplatinacycles, one of which is formed by hydroplatination of the Pt–H bond to the etheno bridge and the other is a vinylic C–H bond activation product, and a five-membered selenaplatinacycle formed by an aromatic C–H bond activation.

Graphical abstract: Thermal reaction of a (hydrido)(selenolato)platinum(ii) complex having a dibenzobarrelenyl group leading to three cyclometalations

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Article information

DOI
https://doi.org/10.1039/C0DT00483A
Article type
Communication
Submitted
17 mai 2010
Accepted
28 mai 2010
First published
08 juin 2010

Dalton Trans., 2010,39, 6181-6183

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Thermal reaction of a (hydrido)(selenolato)platinum(II) complex having a dibenzobarrelenyl group leading to three cyclometalations

A. Ishii, Y. Yamaguchi and N. Nakata, Dalton Trans., 2010, 39, 6181 DOI: 10.1039/C0DT00483A

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