Issue 20, 2019

Ionic liquid cations as methylation agent for extremely weak chalcogenido metalate nucleophiles

Abstract

Selective in situ methylation of terminal chalcogenide ligands of molecular chalcogenido metalate anions in ionothermal reactions with alkylimidazolium-based ionic liquids yields a series of organo-functionalized chalcogenido metalate compounds. We present the syntheses and crystal structures of (C4C1C1Im)4+x[Sn10S16O4(SMe)4][An]x (1a–1f), (dmmpH)6[Mn4Sn4Se13(SeMe)4] (2), and (CnC1Im)6[Hg6Te10(TeMe)2] (3a, 3b). The methylation was confirmed by Raman spectroscopy, and the optical absorption properties of the methylated compounds were determined and compared to purely inorganic analogs.

Graphical abstract: Ionic liquid cations as methylation agent for extremely weak chalcogenido metalate nucleophiles

Supplementary files

Article information

Article type
Edge Article
Submitted
19 mars 2019
Accepted
20 avr. 2019
First published
22 avr. 2019
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2019,10, 5211-5217

Ionic liquid cations as methylation agent for extremely weak chalcogenido metalate nucleophiles

B. Peters, S. Santner, C. Donsbach, P. Vöpel, B. Smarsly and S. Dehnen, Chem. Sci., 2019, 10, 5211 DOI: 10.1039/C9SC01358J

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