Issue 5, 2022

Hydrogenation of cage-opened C60 derivatives mediated by frustrated Lewis pairs

Abstract

Multiply-carbonylated fullerene derivatives were found to work as one component in frustrated Lewis pairs which caused an Si–H bond activation in the presence of B(C6F5)3, leading to the carbonyl hydrogenation in up to 99% yield. The Lewis acid-mediated reductive arylation also took place to furnish a corresponding ketal derivative.

Graphical abstract: Hydrogenation of cage-opened C60 derivatives mediated by frustrated Lewis pairs

Supplementary files

Article information

Article type
Communication
Submitted
04 déc. 2021
Accepted
10 janv. 2022
First published
14 janv. 2022

Org. Biomol. Chem., 2022,20, 1000-1003

Hydrogenation of cage-opened C60 derivatives mediated by frustrated Lewis pairs

Y. Hashikawa and Y. Murata, Org. Biomol. Chem., 2022, 20, 1000 DOI: 10.1039/D1OB02316K

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