Issue 40, 2018

Structural evolution in metallomicroemulsions – the effect of increasing alcohol hydrophobicity

Abstract

Small-angle neutron scattering and contrast variation has been employed to quantify how a series of alcohols with increasing hydrophobicity exert different abilities to structure a model toluene based metallomicroemulsion – a microemulsion system stabilised with a metallosurfactant. Classical microemulsion phase evolution and droplet structure are observed, leading to an oil rich core stabilised by a surfactant film containing a highly concentrated, hydrated metal ion layer.

Graphical abstract: Structural evolution in metallomicroemulsions – the effect of increasing alcohol hydrophobicity

Article information

Article type
Paper
Submitted
18 mai 2018
Accepted
25 juil. 2018
First published
02 août 2018

Dalton Trans., 2018,47, 14211-14217

Structural evolution in metallomicroemulsions – the effect of increasing alcohol hydrophobicity

A. Paul, I. A. Fallis, E. C. Stokes, S. M. King and P. C. Griffiths, Dalton Trans., 2018, 47, 14211 DOI: 10.1039/C8DT02031K

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