Issue 32, 2011
From the journal:

Chemical Communications

Cavitand supported tetraphosphine: cyclodextrin offers a useful platform for Suzuki-Miyaura cross-coupling†‡§

Elena Zaborova,a   Julia Deschamp,a   Samuel Guieu,a   Yves Blériot,a   Giovanni Poli,a   Mickaël Ménand,a   David Madec,*a   Guillaume Prestat*a  and  Matthieu Sollogoub*a  

* Corresponding authors

a UPMC Univ Paris 06, Sorbonne Universités, Institut Universitaire de France, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), FR 2769, C. 181, 4 place Jussieu, 75005 Paris, France
E-mail: matthieu.sollogoub@upmc.fr
Tel: 33 1 44 27 61 63

Abstract

The cyclodextrin-tetraphosphine hybrid coined α-Cytep allows turnover numbers up to 340 000 000 000 and turnover frequencies up to 1 000 000 000 h−1 to be reached in Suzuki–Miyaura reactions. These exceptional figures are clearly linked to the outstanding longevity of the reactive species induced by the ligand α-Cytep and illustrates the rising potential of cyclodextrins in catalytic applications.

Graphical abstract: Cavitand supported tetraphosphine: cyclodextrin offers a useful platform for Suzuki-Miyaura cross-coupling

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C1CC12241J
Article type
Communication
Submitted
18 huhti 2011
Accepted
20 touko 2011
First published
08 heinä 2011

Chem. Commun., 2011,47, 9206-9208

Permissions

Request permissions

Cavitand supported tetraphosphine: cyclodextrin offers a useful platform for Suzuki-Miyaura cross-coupling

E. Zaborova, J. Deschamp, S. Guieu, Y. Blériot, G. Poli, M. Ménand, D. Madec, G. Prestat and M. Sollogoub, Chem. Commun., 2011, 47, 9206 DOI: 10.1039/C1CC12241J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements