Future prospects of high-entropy alloys as next-generation industrial electrode materials

Abstract

The rapid advancement of electrochemical processes in industrial applications has increased the demand for high-performance electrode materials. High-entropy alloys (HEAs), a class of multicomponent alloys with unique properties, have emerged as potential electrode materials owing to their enhanced catalytic activity, superior stability, and tunable electronic structures. This review explores contemporary developments in HEA-based electrode materials for industrial applications and identifies their advantages and challenges as compared to conventional commercial electrode materials in industrial aspects. The importance of tuning the composition, crystal structure, different phase formations, thermodynamic and kinetic parameters, and surface morphology of HEAs and their derivatives to achieve the predicted electrochemical performance is emphasized in this review. Synthetic procedures for producing potential HEA electrode materials are outlined, and theoretical discussions provide a roadmap for recognizing the ideal electrode materials for specific electrochemical processes in an industrial setting. A comprehensive discussion and analysis of various electrochemical processes (HER, OER, ORR, CO₂RR, MOR, AOR, and NRR) and electrochemical applications (batteries, supercapacitors, etc.) is included to appraise the potential ability of HEAs as an electrode material in the near future. Overall, the design and development of HEAs offer a promising pathway for advancing industrial electrode materials with improved performance, selectivity, and stability, potentially paving the way for the next generation of electrochemical technology.