Complex electrochemiluminescence patterns shaped by hydrodynamics at a rotating bipolar electrode

Abstract

Electrochemiluminescence (ECL) is a powerful analytical approach that enables the optical readout of electrochemical processes. Over the last few years, ECL has gained considerable attention due to its large number of applications, including chemical sensing, bioanalysis and microscopy. In these fields, the promotion of ECL at bipolar electrodes has offered unprecedented opportunities thanks to wireless electrochemical addressing. Herein, we take advantage of the synergy between ECL and bipolar electrochemistry (BE) for imaging light-emitting layers shaped by hydrodynamics, polarization effects and the nature of the electrochemical reactions taking place wirelessly on a rotating bipolar electrode. The proof-of-principle is established with the model ECL system [Ru(bpy)₃]²⁺/tri-n-propylamine. Interestingly, the ECL-emitting region moves and expands progressively from the anodic bipolar pole to the cathodic one where ECL reactants should neither be generated nor ECL be observed. Therefore, it shows a completely unusual behavior in the ECL field since the region where ECL reagents are oxidized does not coincide with the zone where ECL light is emitted. In addition, the ECL patterns change progressively to an “ECL croissant” and then to a complete ring shape due to the hydrodynamic convection. Such an approach allows the visualization of complex light-emitting patterns, whose shape is directly controlled by the rotation speed, chemical reactivity and BE-induced polarization. Indeed, the bipolar electrochemical addressing of the electrode breaks the circular symmetry of the reported rotating system. This unexplored and a priori simple configuration yields unique ECL behavior and raises new curious questions from the theoretical and experimental points of view in analytical chemistry. Finally, this novel wireless approach will be useful for the development of original ECL systems for analytical chemistry, studies of electrochemical reactivity, coupling microfluidics with ECL and imaging.