The three-electron δ-bond in 1,6-diazabicyclo[4.4.4]tetradecane radical cation perchlorate is 2.30 Å long; the ![[triple bond, length half m-dash]](https://www.rsc.org/images/entities/char_e007.gif)
N![[triple bond splayed left]](https://www.rsc.org/images/entities/char_e00d.gif)
–N![[triple bond splayed right]](https://www.rsc.org/images/entities/char_e00c.gif)
bond length in 1,6-diazoniatricyclo[4.4.4]tetradecane bistrifluoromethanesulphonate is 1.53 Å.
R. W. Alder, A. G. Orpen and J. M. White, J. Chem. Soc., Chem. Commun., 1985, 949 DOI: 10.1039/C39850000949
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