Reactive methyleneamines bearing alkyl or functional groups are isolated at low temperature in the condensate state by flash vacuum thermolysis of α-aminonitriles and subsequent vapour phase HCN removal on solid base.
J. C. Guillemin and J. M. Denis, J. Chem. Soc., Chem. Commun., 1985, 951 DOI: 10.1039/C39850000951
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