Issue 29, 2019

A biomimetic approach towards phorone sesterterpenoids

Abstract

We report an investigation towards a unified total synthesis of the Korean sponge derived sesterterpenoids, phorones A (1) and B (2), via a biomimetic strategy. This work has established a new synthetic strategy to the parent ansellane sesterterpenoid skeleton with unanticipated diversion to a biogenetically related pathway.

Graphical abstract: A biomimetic approach towards phorone sesterterpenoids

Supplementary files

Article information

Article type
Communication
Submitted
01 abr. 2019
Accepted
15 may. 2019
First published
10 jul. 2019
This article is Open Access
Creative Commons BY license

Org. Biomol. Chem., 2019,17, 6985-6988

A biomimetic approach towards phorone sesterterpenoids

H. J. Shirley and C. D. Bray, Org. Biomol. Chem., 2019, 17, 6985 DOI: 10.1039/C9OB00745H

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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